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Tris(acetylacetonato-$k^2O,O')$(1,10-phenanthroline-$k^2N,N')$erbium(III)

Neelgund, Gururaj M and Shivashankar, SA and Narasimhamurthy, T and Rathore, RS (2007) Tris(acetylacetonato-$k^2O,O')$(1,10-phenanthroline-$k^2N,N')$erbium(III). In: Acta Crystallographica Section C: Crystal Structure Commuications, 63 (2). m74-m76.

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Abstract

The title compound, $[Er(C_5H_7O_2)_3(C_{12}H_8N_2)]$, is a mixedligand metal-organic precursor for chemical vapour deposition, with the Er atom being eight-coordinate. The coordination polyhedron, described as a distorted square antiprism, is formed by three bidentate (chelating) acetylacetonate residues and a phenanthroline ligand in the apical positions. Molecular assembly via $C-H^{...}O$ hydrogen bonds generates a sheet structure in the ac plane.Weak co-operative $C-H^{...}\pi$ interactions form molecular dimers and contribute to the stability of the intersheet packing. The supramolecular assembly contains voids which form hydrophobic porous channels, surrounded by a cluster of dimers.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to International Union of Crystallography.
Department/Centre: Division of Chemical Sciences > Materials Research Centre
Date Deposited: 27 Jun 2007
Last Modified: 19 Sep 2010 04:36
URI: http://eprints.iisc.ernet.in/id/eprint/10244

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