Muktha, B and Srinivas, O and Amresh, MR and Row, Guru TN and Jayaraman, N and Sekar, K (2004) Corrigendum to ‘The crystal structure of 1,2,3,4,6-penta-O-benzoyl-\alpha-D-mannopyranose: observation of C–H...\pi interaction as a surrogate to O–H...O interaction of a free sugar’. In: Carbohydrate Research, 339 (2). pp. 435-436.
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The crystal structure of the title compound was determined by X-ray crystallography. The compound crystallized in the orthorhombic space group $P2_12_12_1$ with four molecules in the unit cell with a=9.170(2), b=9.873 (2), c=38.831(8) Å. The structure was refined to a R index of 0.041 for 7907 independent reflections. The mannopyranose unit adopts a distorted $^4C_1$ conformation. The structure depicts unique network of C---H...\pi interactions, very closely resembling the pattern of O---H...Ointeractions in free sugars. This intriguing and rare observation points to a notion that the supramolecular organization pertaining to a sugar is in-built in the pyranose ring itself.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to Elsevier|
|Keywords:||Conformation; Crystal structures; C---H...\pi interaction; Hydrogen bonding; \alpha -D-Mannose; Pyranose|
|Department/Centre:||Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Division of Information Sciences > BioInformatics Centre
Division of Chemical Sciences > Organic Chemistry
|Date Deposited:||28 Jun 2007|
|Last Modified:||19 Sep 2010 04:36|
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