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Electronic structures of $RN(PX_2)_2$ $(R=CH_3 or C_6H_5; X=Cl, OCH_3 or OC_6H_5)$ ligands: an ultraviolet photoelectron spectroscopic study

Pradeep, T and Hegde, MS and Balakrishna, MS and Krishnamurthy, SS (1990) Electronic structures of $RN(PX_2)_2$ $(R=CH_3 or C_6H_5; X=Cl, OCH_3 or OC_6H_5)$ ligands: an ultraviolet photoelectron spectroscopic study. In: Journal of Electron Spectroscopy and Related Phenomena, 53 (3). pp. 119-127.

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Official URL: http://dx.doi.org/10.1016/0368-2048(90)80326-6

Abstract

Vapour phase HeI photoelectron spectra of the diphosphazane ligands $RN(PX_2)_2$ $(R=CH_3 or C_6H_5, X=Cl, OCH_3 or OC_6H_5)$ are presented along with the assignments of bands on the basis of molecular orbital calculations. The spectra are in accordance with the structural studies which indicate multiple bonding in the $P-N-P$ segment. The phosphorus lone pair ionization energy appears to follow the a donor ability of the ligands.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier Science.
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 02 Jul 2007
Last Modified: 18 Jan 2012 07:02
URI: http://eprints.iisc.ernet.in/id/eprint/11342

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