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A new method for the synthesis of chromium(iv) oxide at ambient pressure

Ramesha, K and Gopalakrishnan, J (1999) A new method for the synthesis of chromium(iv) oxide at ambient pressure. In: Chem. Commun.,, 13 . 1173 -1174.

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Abstract

The reaction CrO3 + 2NH4X ? CrO2 + 2 NH3 + H2O + X2 (X = Br, I), which occurs quantitatively at 120–150 °C,provides a convenient method for the synthesis of CrO2;unlike conventional methods, the method reported here does not require the use of high pressure for the synthesis of this technologically important material.

Item Type: Journal Article
Additional Information: Copyright for this article belongs to The Royal Society
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 26 Jul 2004
Last Modified: 19 Sep 2010 04:14
URI: http://eprints.iisc.ernet.in/id/eprint/1144

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