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Single-crystal to single-crystal phase transitions of bis(N-phenylisonicotinamide)silver(I) nitrate reveal cooperativity properties in porous molecular materials

Mukherjee, Partha S and Nazario, Lopez and Atta M, Arif and Cervantes-Lee, Francisco and Noveron, Juan C (2007) Single-crystal to single-crystal phase transitions of bis(N-phenylisonicotinamide)silver(I) nitrate reveal cooperativity properties in porous molecular materials. In: Chemical Communications (14). pp. 1433-1435.

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Abstract

Two single-crystal to single-crystal phase transitions in trans- $[Ag(NPI)_2](NO_3).2CH_3OH (1a)$, (NPI = N- phenylisonicotinamide) were characterized with X-ray crystallography; the first transition is reversible and arises from a desolvation transition induced by vacuum and generated 1b; the second transition was induced by heat at $140^oC$ and generated 1c.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Royal Sciety of Chemistry.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 12 Jul 2007
Last Modified: 25 Jan 2012 05:02
URI: http://eprints.iisc.ernet.in/id/eprint/11459

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