Thangadurai, V and Subbanna, GN and Gopalakrishnan, J (1998) Ln28Ti2O7 (Ln = La, Nd, Sm, Gd): a novel series of defective Ruddlesden–Popper phases formed by topotactic dehydration of HLnTiO4. In: Chem. Commun., 12 . pp. 1299-1300.
Topotactic dehydration of HLnTiO4 (Ln = La, Nd, Sm or Gd) around 480–500 °C yields a new series of metastable layered perovskite oxides, Ln28Ti2O7, that possess a defective Sr3Ti2O7 structure, where the cubooctahedral sites within the double-perovskite layers are most likely vacant.
|Item Type:||Journal Article|
|Additional Information:||Copyright for this article belongs to Royal Society Of Chemistry.|
|Department/Centre:||Division of Chemical Sciences > Materials Research Centre
Division of Chemical Sciences > Solid State & Structural Chemistry Unit
|Date Deposited:||23 Jul 2004|
|Last Modified:||02 May 2011 07:01|
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