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Aromatics to Polyquinanes: A General Method for the Construction of Tricyclo$[6.3.0.0^{4,8}]$-and Tricyclo$[6.3.0.0^{2,6}]$ undecanes

Biju, John P and Rao, Subba GSR (1999) Aromatics to Polyquinanes: A General Method for the Construction of Tricyclo$[6.3.0.0^{4,8}]$-and Tricyclo$[6.3.0.0^{2,6}]$ undecanes. In: Tetrahedron Letters, 40 (52). pp. 9379-9382.

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Abstract

The conversion of aromatic compounds to linear and angular triquinanes is described and involves a 5-exo-trig-allyl radical cyclization as the key reaction for constructing the strained ketones 9 and 18, which are then transformed into the quinanes 12 and 23, respectively.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 28 Sep 2007
Last Modified: 19 Sep 2010 04:39
URI: http://eprints.iisc.ernet.in/id/eprint/11965

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