Aromatics to Polyquinanes: A General Method for the Construction of Tricyclo$[6.3.0.0^{4,8}]$-and Tricyclo$[6.3.0.0^{2,6}]$ undecanes

Biju, John P and Rao, Subba GSR (1999) Aromatics to Polyquinanes: A General Method for the Construction of Tricyclo$[6.3.0.0^{4,8}]$-and Tricyclo$[6.3.0.0^{2,6}]$ undecanes. In: Tetrahedron Letters, 40 (52). pp. 9379-9382.

PDF Aromatics_to_polyquinanes.pdf Restricted to Registered users only Download (199Kb) | Request a copy

Abstract

The conversion of aromatic compounds to linear and angular triquinanes is described and involves a 5-exo-trig-allyl radical cyclization as the key reaction for constructing the strained ketones 9 and 18, which are then transformed into the quinanes 12 and 23, respectively.

Item Type:	Journal Article
Additional Information:	Copyright of this article belongs to Elsevier.
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	28 Sep 2007
Last Modified:	19 Sep 2010 04:39
URI:	http://eprints.iisc.ernet.in/id/eprint/11965

Actions (login required)

View Item