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Stereospecific construction of three contiguous quaternary carbon atoms. Synthesis of (±)-3-methoxythaps-8-ene

Srikrishna, A and Ramachary, DB (2002) Stereospecific construction of three contiguous quaternary carbon atoms. Synthesis of (±)-3-methoxythaps-8-ene. In: Tetrahedron Letters, 43 (15). pp. 2765-2768.

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Abstract

Synthesis of (±)-3-methoxythapsene via stereospecific construction of three contiguous quaternary carbon atoms, employing a combination of a Claisen rearrangement and an intramolecular diazoketone cyclopropanation as key reactions, is described.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier Science Ltd.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 03 Oct 2007
Last Modified: 19 Sep 2010 04:39
URI: http://eprints.iisc.ernet.in/id/eprint/12007

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