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An enantiospecific synthesis of (−)-2-pupukeanone via a rhodium carbenoid C---H insertion reaction

Srikrishna, A and Gharpure, Santosh J and Kumar, Ravi P (2001) An enantiospecific synthesis of (−)-2-pupukeanone via a rhodium carbenoid C---H insertion reaction. In: Tetrahedron Letters, 42 (23). pp. 3929-3931.

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Abstract

An enantiospecific synthesis of (−)-2-pupukeanone, starting from (R)-carvone employing a Michael–Michael reaction and an intramolecular rhodium carbenoid C---H insertion reaction as the key steps for the generation of the isotwistane framework, is described.

Item Type: Journal Article
Additional Information: copyright of this article belongs to Elsevier Science Ltd.
Keywords: Biochemistry;Molecular Biophysics
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 13 Oct 2007
Last Modified: 19 Sep 2010 04:40
URI: http://eprints.iisc.ernet.in/id/eprint/12275

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