Mehta, Goverdhan and Nandakumar, Jayakrishnan (2002) Novel tandem ring-opening/ring-closing metathesis reactions of functionalized cyclohexenoids derived from (−)-alpha-pinene. In: Tetrahedron Letters, 43 (4). pp. 699-702.
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Abstract
The cyclohexenone (+)-2, readily obtained from (−)-alpha-pinene 1 was elaborated to (+)-3 in an attempt to construct the AB rings of taxoids employing the ring-closure metathesis (RCM) reaction as the key step. In the event, a novel ring-opening/ring-closing metathesis reaction was encountered in the relatively strain free cyclohexenyl ring of (+)-3.
| Item Type: | Journal Article |
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| Additional Information: | Copyright for this article belongs to Elsevier Science. |
| Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
| Date Deposited: | 03 Aug 2004 |
| Last Modified: | 19 Sep 2010 04:14 |
| URI: | http://eprints.iisc.ernet.in/id/eprint/1229 |
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