Mehta, Goverdhan and Singh, Robindro S and Gagliardini, Vanessa and Priyakumar, Deva U and Sastry, Narahari G (2001) The bicyclo[2.1.1]hexan-2-one system: a new probe for the experimental and computational study of electronic effects in pi-facial selectivity in nucleophilic additions. In: Tetrahedron Letters, 42 (48). pp. 8527-8530.
The remotely substituted 5-exo-bicyclo[2.1.1]hexan-2-one system is introduced as a new probe to study long range electronic effects on pi-face selectivity during hydride reduction and a systematic computational study demonstrates good predictability at the semi-empirical level.
|Item Type:||Journal Article|
|Additional Information:||Copyright for this article belongs to Elsevier Science.|
|Department/Centre:||Division of Chemical Sciences > Organic Chemistry|
|Date Deposited:||05 Aug 2004|
|Last Modified:||19 Sep 2010 04:14|
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