Pradeep, T and Rao, CNR (1990) Electronic Transitions of Hydrogen Bonded Complexes: An Electron Energy Loss Spectroscopic Study. In: Journal of Molecular Structure, 224 . pp. 21-31.
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Electronic spectra of hydrogen bonded complexes have been studied by electron energy loss spectroscopy and assignments made based on experimental orbital energies from HeI photoelectron spectra and molecular orbital calculations. Electronic transitions of diethyl ether-HCl and $SO_2$·HCl complexes show small shifts from those of HCl and the free electron donor, as expected of weakly interacting systems. Electronic spectra of the dimers of formic and acetic acids are markedly different from those of the monomers. Dimers show characteristic $ n\rightarrow\pi^\ast$ and $\pi\rightarrow\pi^\ast$ transitions in the 7–11 eV region.
|Item Type:||Journal Article|
|Additional Information:||copyright of this article belongs to Elsevier Science B.V.|
|Keywords:||Electronic transitions;electron energy|
|Department/Centre:||Division of Chemical Sciences > Solid State & Structural Chemistry Unit|
|Date Deposited:||19 Nov 2007|
|Last Modified:||19 Sep 2010 04:41|
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