Srikrishna, A and Hemamalini, P (1990) Radical Cyclization Strategies to Bridged Systems. Synthesis of Bicyclo[3.2.1]octan-3-ones from (S)-Carvone. In: Journal of Organic Chemistry, 55 (16). pp. 4883-4887.
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Radical cyclization of the bromo enones I (R = H, R1R2 = O, R3 = Me, Et, H, Ac, CH2Ph), obtained by regiospecific bromoetherification at the electron-rich double bond of (S)-carvone, gave regio- and stereospecificially bicyclo[3.2.1]octan-3-ones II (R = H, R1R2 = O; R3 as above). Analogously, radical cyclizations of I (R = R1 = H, R2 = OH) gave II (R = R1 = H, R2 = OH) and I (R = Me, R1R2 = O) gave II (R = Me, R1R2 = O).
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to ACS publications|
|Department/Centre:||Division of Chemical Sciences > Organic Chemistry|
|Date Deposited:||20 Dec 2007|
|Last Modified:||19 Sep 2010 04:41|
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