ePrints@IIScePrints@IISc Home | About | Browse | Latest Additions | Advanced Search | Contact | Help

The first enantiospecific synthesis of (+)-10,11-epoxythapsan-10-ol: revision of the absolute stereochemistry of thapsanes

Srikrishna, A and Anebouselvy, K (2002) The first enantiospecific synthesis of (+)-10,11-epoxythapsan-10-ol: revision of the absolute stereochemistry of thapsanes. In: Tetrahedron-Letters, 43 (30). pp. 5261-5264.

[img] PDF
pradeep.6.pdf
Restricted to Registered users only

Download (83Kb) | Request a copy

Abstract

The first enantiospecific synthesis of (+)-cis,anti,cis-1,8,12,12-tetramethyl-4-oxatricyclo[6.4.0.02,6]dodecan-3-ol (+)-1g, an enantiomer of natural thapsane isolated from Thapsia villosa var minor, is accomplished starting from (R)-carvone, which revises the absolute stereochemistry of natural thapsanes.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier Science Ltd.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 27 Dec 2007
Last Modified: 19 Sep 2010 04:41
URI: http://eprints.iisc.ernet.in/id/eprint/12582

Actions (login required)

View Item View Item