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Synthesis based on cyclohexadienes: Part 4. Novel synthesis of the 6-aryl-2,4-dimethoxybenzoates. Alternariol and methyl trimethylaltenusin

Kanakam, Charles C and Mani, NS and Rao, Subba GSR (1990) Synthesis based on cyclohexadienes: Part 4. Novel synthesis of the 6-aryl-2,4-dimethoxybenzoates. Alternariol and methyl trimethylaltenusin. In: Journal of the Chemical Society, Perkin Transactions, 1 (8). pp. 2233-2237.

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Abstract

A novel method for the preparation of 6-aryl-2,4-dimethoxybenzoic acids involving the Alder–Rickert reaction of 1,5-dimethoxycyclohexa-1,4-dienes and arylpropiolic esters is described. This strategy has been extended to the synthesis of the mould metabolite alternariol and methyl trimethylaltenusin.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Royal Society of Chemistry
Keywords: Novel synthesis
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 01 Feb 2008
Last Modified: 19 Sep 2010 04:41
URI: http://eprints.iisc.ernet.in/id/eprint/12619

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