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The influence of some fluoroanions on the anodic oxidation of chlorate ion to perchlorate ion at a lead dioxide electrode

Munichandraiah, N and Sathyanarayana, S (1990) The influence of some fluoroanions on the anodic oxidation of chlorate ion to perchlorate ion at a lead dioxide electrode. In: Journal of Applied Electrochemistry, 20 (6). pp. 1059-1062.

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Abstract

Both NaF and $Na_3A_lF_6$ catalyze the anodic oxidn. of chlorate ion to perchlorate ion at a$\beta-PbO_2$ coated titanium electrode. $Na_2SiF_6$ and $Na_2TiF_6$ do not affect the reaction. However, NaBF4 and NaPF6 retard this reaction. It is demonstrated that the fluorocompounds influence the overpotential of the chlorate oxidn. reaction more than that of oxygen evolution, thus resulting in either electrocatalysis or retardation of the reaction.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Chapman and Hall Ltd.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 30 Jan 2008
Last Modified: 05 Jan 2011 07:36
URI: http://eprints.iisc.ernet.in/id/eprint/12628

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