Vyas, K and Manohar, H and Venkatesan, K (1990) Thermally induced O to N acyl migration in the salicylamides: thermal motion analysis of the reactants. In: Journal of Physical Chemistry, 94 (15). pp. 6069-6073.
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Anal. of thermal motion, using the anisotropic displacement parameters obtained from x-ray crystal structure anal., has been employed to understand the thermally induced O to N acyl migration reaction in salicylamides. Application of rigid-bond criterion reveals considerable internal motion in the mol. The large mean square displacement amplitude between the amide N and acyl C atom and the significant libration of the acyloxy group are consistent with the intramol. mechanism proposed earlier form x-ray crystallog. studies.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to American Chemical Society|
|Keywords:||salicylamides;thermal motion;anisotropic displacement|
|Department/Centre:||Division of Chemical Sciences > Organic Chemistry
Division of Chemical Sciences > Inorganic & Physical Chemistry
|Date Deposited:||08 Feb 2008|
|Last Modified:||19 Sep 2010 04:41|
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