Devendra, KS and Balasubrahmanyam, SN and Prasad, N (1990) E-Z Isomerization in ethyl cyano(hydrazono)acetate, a push-pull imine. In: Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 29 (9). pp. 804-810.
Full text not available from this repository. (Request a copy)Abstract
Transformation of the E form of Et cyanoglyoxalate phenylhydrazone (E-I) into Z-I is catalyzed by proton-acceptor-type H-bonding solvents (H-bonding bases). Kinetic and allied data gathered on the approach of E-I towards equil. with Z-I in acetone have been utilized to delimit possible processes by which acetone may catalyze the transformation, under the basic premise that a consequence of H-bonding by the base solvent is enhancement of electron d. at amino N.
| Item Type: | Journal Article |
|---|---|
| Additional Information: | The copyright belongs to National Institute of Science Communication and Information Resources |
| Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
| Date Deposited: | 19 Feb 2008 |
| Last Modified: | 27 Aug 2008 13:07 |
| URI: | http://eprints.iisc.ernet.in/id/eprint/12675 |
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