Sreenivasulu, M and Rao, Krishna GS (1989) Vilsmeier reaction studies on some $\alpha$ .$\beta$ -unsaturated alkenones. In: Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 28B (6). pp. 494-495.Full text not available from this repository. (Request a copy)
$\alpha$ ,$\beta$-Unsatd. alkenones were converted into chlorobenzenemono-, di- and tricarboxaldehydes under Vilsmeier reaction conditions. Besides six known chlorobenzaldehydes the route gave, in a one-pot reaction, two new members of this class of compds., 3-methyl- and 3,5-dimethyl-2-chlorobenzaldehydes. E.g., 2-hexen-4-one gave 20% 4-chloro-5-methylisophthaldehyde (I).
|Item Type:||Journal Article|
|Department/Centre:||Division of Chemical Sciences > Organic Chemistry|
|Date Deposited:||12 Feb 2008|
|Last Modified:||27 Aug 2008 13:08|
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