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Microscopic expression for time-dependent solvation energy of ions and dipoles in dense polar liquids

Chandra, Amalendu and Bagchi, Biman (1989) Microscopic expression for time-dependent solvation energy of ions and dipoles in dense polar liquids. In: Proceedings of the Indian Academy of Sciences - Chemical Sciences, 101 (1). pp. 83-88.

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Abstract

Microscopic expressions for the time dependence of solvation energies of newly created ions and dipoles in a dense dipolar liquid are presented. The dynamics of solvation of an ion differ considerably from that of a dipole, especially that the long wavelength (k = 0) component of solvent response is totally absent for dipoles. The translational modes of the solvent molecules lead to a breakdown of Onsager's conjecture on the distance dependence of solvent polarization relaxation.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Indian Academy of Sciences. The journal is currently known as Journal of Chemical Sciences.
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 19 Feb 2008
Last Modified: 19 Sep 2010 04:42
URI: http://eprints.iisc.ernet.in/id/eprint/12935

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