Chandra, Amalendu and Bagchi, Biman (1989) Microscopic expression for time-dependent solvation energy of ions and dipoles in dense polar liquids. In: Proceedings of the Indian Academy of Sciences - Chemical Sciences, 101 (1). pp. 83-88.
Microscopic expressions for the time dependence of solvation energies of newly created ions and dipoles in a dense dipolar liquid are presented. The dynamics of solvation of an ion differ considerably from that of a dipole, especially that the long wavelength (k = 0) component of solvent response is totally absent for dipoles. The translational modes of the solvent molecules lead to a breakdown of Onsager's conjecture on the distance dependence of solvent polarization relaxation.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to Indian Academy of Sciences. The journal is currently known as Journal of Chemical Sciences.|
|Department/Centre:||Division of Chemical Sciences > Solid State & Structural Chemistry Unit|
|Date Deposited:||19 Feb 2008|
|Last Modified:||19 Sep 2010 04:42|
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