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Asymmetric allylation of aldehydes with chiral platinum phosphinite complexes

Sharma, Rakesh K and Samuelson, Ashoka G (2007) Asymmetric allylation of aldehydes with chiral platinum phosphinite complexes. In: Tetrahedron: Asymmetry, 18 (20). pp. 2387-2393.

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Platinum phosphinite complexes made from chiral diols catalyze the enantioselective allylation of cinnamaldehyde. This reaction proceeds with better yields at shorter reaction times in the presence of acetic acid. Enantiomeric excesses were greater when reactions were carried out with phosphinite ligands having hydrogen bond donors or acceptors.

Item Type: Journal Article
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Additional Information: Copyright of this article belongs to Elsevier Ltd.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 04 Feb 2008
Last Modified: 19 Sep 2010 04:42
URI: http://eprints.iisc.ernet.in/id/eprint/12965

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