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Radical cyclizations in the synthesis of natural products

Srikrishna, A (1987) Radical cyclizations in the synthesis of natural products. In: Current Science, 56 (9). pp. 392-396.

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Abstract

Organic chemists have began to use intramolecular radical addition reactions i.e. radical cyclization to develop useful synthetic transformations.The mild reactions conditions and the observed selectivities made these radical cyclizaiona a viable alternative to the conventional polar reactions.Applicatin of polar radical cyclization strategy to various natural products like sesquiterpenes (sativenes,agarofuransm,hirsutene,capnellenes,silphiperfolene, seychellene,patchoulli alcohol),marine deterpene isoamijiol, pyrrolizidine alkaloids. (dehydrohastanecine,heliotridine,hastanecine), by various organic chemists demonstrates the versatility of this relatively new area in organic synthesis.

Item Type: Journal Article
Additional Information: The copyright belongs to Indian Academy of Sciences
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 27 Feb 2008
Last Modified: 19 Sep 2010 04:42
URI: http://eprints.iisc.ernet.in/id/eprint/13105

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