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Consequences of lattice relaxability in solid state photodimerizations

Murthy, GS and Arjunan, P and Venkatesan, K and Ramamurthy, V (1987) Consequences of lattice relaxability in solid state photodimerizations. In: Tetrahedron, 43 (7). pp. 1225-1240.

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Abstract

With the view to understand the photobehavior of olefinic cryst. compds. lattice energy calcns. have been performed for a no. of photodimerizable olefins. It is shown that to rationalize the photoreactivity of the compds., dynamic topochem. concepts have to be invoked. Although the calcns. have been carried out using the ground state geometry with the dispersion consts. applicable to the ground state, the results are in agreement with the exptl. observations. The limitations of the approach employed are pointed out.

Item Type: Journal Article
Additional Information: The copyright belongs to Pergamon journals Ltd.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 19 Mar 2008
Last Modified: 19 Sep 2010 04:43
URI: http://eprints.iisc.ernet.in/id/eprint/13231

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