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Vilsmeier reaction of some 1-methoxy-1,4-cyclohexadienes: a convenient route to polyformylbenzenes

Rao, Raju B and Krishna, GS (1985) Vilsmeier reaction of some 1-methoxy-1,4-cyclohexadienes: a convenient route to polyformylbenzenes. In: Synthesis, 8 . pp. 779-781.

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Abstract

Vilsmeier reaction of methoxycyclohexadienes by DMF/POCl3 gave di- and triformylbenzenes. The reaction involved multiple attack of the electrophilic Vilsmeier complex on the double bonds of the methoxycyclohexadienes, hydrolysis to formyl groups, air oxidation., and in some cases, an addition elimination sequence.

Item Type: Journal Article
Additional Information: Copyright belongs to Thieme Medical Publishers
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 20 Mar 2008
Last Modified: 27 Aug 2008 13:16
URI: http://eprints.iisc.ernet.in/id/eprint/13448

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