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$^1H NMR$ and a Study of the Anomalous Temperature Dependence of the $^{35}Cl NQR$ Frequencies in 2-chloro-3-Pyridinol

Raghoottama, PS and Soundararajan, S and Ramakrishna, J (1987) $^1H NMR$ and a Study of the Anomalous Temperature Dependence of the $^{35}Cl NQR$ Frequencies in 2-chloro-3-Pyridinol. In: Magnetic Resonance in Chemistry, 25 (7). pp. 572-574.

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Abstract

A $^{35}Cl NQR$ study of 2-chloro-3-pyridinol showed the presence of four NQR signals at 77 K. One of the lines showed a positive temperature coefficient of the NQR frequency. $^1H NMR$ studies showed the presence of intramolecular hydrogen bonding, and the anomalous NQR temperature dependence has been explained in terms of Bayer and hydrogen bond effects. The room temperature x-ray structure and the low-temperature NQR data suggest the presence of a phase transition.

Item Type: Journal Article
Additional Information: Copyright belongs to John Wiley and Sons
Keywords: Anomalous temperature;dependence Hydrogen bonding;proton NMR
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 25 Mar 2008
Last Modified: 19 Sep 2010 04:43
URI: http://eprints.iisc.ernet.in/id/eprint/13466

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