Padmanabhan, Kaillathe and Dopp, Dietrich and Venkatesan, Kailasam and Ramamurthy, Vaidyanathan (1986) Solid-state Photochemistry of Nitro Compounds: Structure-Reactivity Correlations. In: Journal of the Chemical Society, Perkin Transactions 2 (24). 897 -906.
The molecu lar structures of 1 -t - butyl- 3,5-dimethyl-2,4,6- trinitrobenzene, 1 - t - butyl-3,4,5- trimethyl - 2'6 -dinitrobenzene, and 1 -t-butyl-4-acetyl-3,5-dimethyl-,6-dinitrobenzene have been determined by single-crystal X-ray analyses with a view to establishing a structure-reactivity relationship in the photochemical intramolecular hydrogen-abstraction process in the solid state. The reactivity of these aromatic nitro compounds in the solid state has been rationalized in terms of relevant intramolecular geometrical parameters as well as intermolecular packing considerations.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to Royal Society of Chemistry.|
|Department/Centre:||Division of Chemical Sciences > Organic Chemistry|
|Date Deposited:||01 Apr 2008|
|Last Modified:||19 Sep 2010 04:44|
Actions (login required)