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Laser Raman spectra of single crystals of orthorhombic potassium, rubidium, and cesium perchlorates

Seetharaman, S and Shripathi, T and Srinivasan, V (1983) Laser Raman spectra of single crystals of orthorhombic potassium, rubidium, and cesium perchlorates. In: Nuclear Physics and Solid State Physics Symposium, pp. 369-372.

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Abstract

Laser Raman spectra were recorded for $KClO_4$, $RbClO_4$, and $CsClO_4$ for all 6 necessary orientations in the range 50-1200 $cm^{-1}$. In the 50-400 $cm^-1$ region the low frequency lines are attributed to lattice vibrations whereas the high frequency lines are librational. In the 400-1200 $cm^{-1}$ region the cation effects on $ClO_{4-}$ frequencies is insignificant. The doubly degenerate vibration \nu$^2$ does not show any splitting. The triply degenerate vibration $\nu$s shows a splitting ranging from 28 to 40$cm^{-1}$.

Item Type: Conference Paper
Additional Information: Copyright of this article belongs to American Chemical Society.
Department/Centre: Division of Physical & Mathematical Sciences > Physics
Date Deposited: 10 Apr 2008
Last Modified: 27 Aug 2008 13:18
URI: http://eprints.iisc.ernet.in/id/eprint/13597

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