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Vilsmeier-Haack reaction on some 3-buten-2-ols

Sreenivasulu, M and Rao, Krishna GS (1987) Vilsmeier-Haack reaction on some 3-buten-2-ols. In: Indian Journal of Chemistry, Sect. B: Organic Chemistry including Medicinal Chemistry, 26 (12). pp. 1187-1188.

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Abstract

Vilsmeier-Haack reaction of $R_7R_8C:C(R_9)C(OH)(R_{10})CHR_{11}R_{12} (R_7, R_9, R_{10}, R_{12} = H, Me$; $R_8 = Me, Et, Pr, H$; $R_{11} = H, Me, Et)$ gave 6-26% benzenes I $(R_1 = CHO$; $R_2, R_4, R_6 = H, Me$; $R_3 = Me, CHO$; $R_5 = H, Me, Et, CHO)$. The presence of at least 5 appropriate participating C atoms on the butenol backbone was essential for formylative benzocyclization to occur.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Council of Scientific & Industrial Research
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 17 Apr 2008
Last Modified: 27 Aug 2008 13:20
URI: http://eprints.iisc.ernet.in/id/eprint/13755

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