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Photolysis of 1,2-naphthoquinone-1-methide dimers

Kasturi, TR and Reddy, Amruta P and Raju, GJ (1987) Photolysis of 1,2-naphthoquinone-1-methide dimers. In: Indian Journal of Chemistry, Sect. B: Organic Chemistry including Medicinal Chemistry, 26 (12). pp. 1171-1172.

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Abstract

Naphthoquinonemethide dimers I $(R=H, Br, CMe_3)$ on photolysis isomerized to the phenolic phenalene derivatives II (same $R; R_1=H)$ via a $\beta-C-O$ cleavage. Methylation and acetylation of II $(R=CMe_3, R_1=H)$ gave II $(R=CMe_3; R_1=Me, Ac)$.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to National Institute of Science Communication and Information Resources, CSIR.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 06 May 2008
Last Modified: 27 Aug 2008 13:21
URI: http://eprints.iisc.ernet.in/id/eprint/13823

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