Kalbandkeri, RG and Padma, DK and Murthy, Vasudeva AR (1984) Reactions of potassium bifluoride with phosphorus halides. In: Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical, 23 (12). pp. 990-991.Full text not available from this repository. (Request a copy)
The reaction of $KHF_2$ with $PX_3$ (X=Br, Cl) in $CH_3CN$ gave $PF_3$. $POX_3$ reacted with $KHF_2$ in $CH_3CN$ at room temperature to give $KPO_2F_2$ and $KPF_6$. Similarly, $KPS_2F_2$ and $KPF_6$ were obtained in reaction between $PSCl_3$ and $KHF_2$ in $CH_3CN$. The products were characterized by their IR spectra and chemical analyses.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to Council of Scientific & Industrial Research.|
|Department/Centre:||Division of Chemical Sciences > Inorganic & Physical Chemistry|
|Date Deposited:||07 May 2008|
|Last Modified:||27 Aug 2008 13:21|
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