Prasad, Durga M and Sathyanarayana, S (1987) Open circuit voltage recovery of discharged and shorted nickel-cadmium cells. In: Journal of Applied Electrochemistry, 17 (3). pp. 463-472.
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The open circuit voltage recovery transient of a positive-limited nickel-cadmium cell has been theoretically analysed taking into account the double-layer charging process, polarization due to charge transfer, mass transfer and ohmic resistance in the cell, and self-discharge due to any internal electronic short. Expressions have been obtained for charge transfer and mass transfer polarization. Experimental data on open circuit voltage recovery transients obtained for nickel-cadmium cells indicate that the rate of the electrode reaction at the positive electrode of the cells is controlled by mass transfer process.
|Item Type:||Journal Article|
|Additional Information:||Copyright for this article belongs to Springer.|
|Department/Centre:||Division of Chemical Sciences > Inorganic & Physical Chemistry|
|Date Deposited:||07 May 2008|
|Last Modified:||19 Sep 2010 04:44|
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