Mishra, AK and Rangarajan, SK (1987) Many-Body Effects in Electrochemisorption Part II. Operator Averages and MF-HF Limits. In: Journal of Electroanalytical Chemistry, 229 (1-2). pp. 67-86.
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The formalism developed in Part I, when approximated, leads to certain operator averages to be evaluated. Simple schemes for obtaining such averages - the mean field correlation approach (MFCA) and the correlation approach (CA) - are outlined. As a zeroth approximation, the Hartree-Fock/mean field case is deduced and compared with the results of Schmickler et al. Some relevant results of the many-body theory are recalled in the Appendix.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to Elsevier Science.|
|Department/Centre:||Division of Chemical Sciences > Inorganic & Physical Chemistry|
|Date Deposited:||23 Jun 2008|
|Last Modified:||19 Sep 2010 04:45|
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