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Pathways in the Nucleophilic Substitution Reactions of Halogenocyclophosphazenes and Subtle Aspects of the Mechanism of Formation of Bicyclic Phosphazenes

Swamy, PY Narayana and Ganapathiappan, S and Swamy, Kumara KC and Krishnamurthy, SS (1987) Pathways in the Nucleophilic Substitution Reactions of Halogenocyclophosphazenes and Subtle Aspects of the Mechanism of Formation of Bicyclic Phosphazenes. In: Phosphorus and Sulfur and the Related Elements, 30 (1-2). pp. 429-432.

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Abstract

Both associative $[S_N2(P)]$ and dissociative $[S_N1(P) and E_1CB]$ mechanisms have been established for the amination reactions of haloenocyclophosphazenes from synthetic and kinetic studies. Several intricate details concerning the formation of bicyclic phosphazenes have been unravelled.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Taylor and Francis.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 13 Jun 2008
Last Modified: 27 Aug 2008 13:26
URI: http://eprints.iisc.ernet.in/id/eprint/14269

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