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Trithiadiazyl hexafluoroarsenates $S_3N_2X^+AsF_6^-$

Padma, DK and Mews, R (1987) Trithiadiazyl hexafluoroarsenates $S_3N_2X^+AsF_6^-$. In: Zeitschrift fuer Naturforschung, B: Chemical Sciences, 42 (6). pp. 699-702.

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Abstract

The prepration is reported of $S_3N_2X[AsF_6]$ by 3 different methods: (a) reaction of $S_3N_2Cl_2$ with $AgAsF_6$ to give $S_3N_2Cl[AsF_6]$, (b) halogen or radical additon to $S_3N_2[AsF_6]$ to give $S_3N_2Br[AsF_6]$ or $S_3N_2ON(CF_3)_2[AsF_6]$, and (c) cycloaddition of NSF to the $NS^{2+}$-cation to give $S_3N_2F[AsF_6]$.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Tuebingen : Verlag der Zeitschrift fuer Naturforschung
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 12 Jun 2008
Last Modified: 27 Aug 2008 13:27
URI: http://eprints.iisc.ernet.in/id/eprint/14289

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