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Studies in terpenoids. Part LXVII. Sesquiterpenic indans of bicyclonidorellane skeleton: synthesis of 1,6-diisopropylindan and ethyl 2-(6-isopropyl-1-indanyl)propionate

Sarma, Prasad MS and Rao, Krishna GS (1986) Studies in terpenoids. Part LXVII. Sesquiterpenic indans of bicyclonidorellane skeleton: synthesis of 1,6-diisopropylindan and ethyl 2-(6-isopropyl-1-indanyl)propionate. In: Indian Journal of ChemistrySection B: Organic Chemistry Including Medicinal Chemistry, 25B (9). pp. 953-954.

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Abstract

Et bicyclonidorellaurinate (I), a sesquiterpenic indan related to the naturally occurring nidorellaurinate (II), was obtained from 6-isopropylindan-1-one (III) by Reformatsky reaction, followed by hydrogenation. The parent bicyclonidorellane (IV) was obtained from III via a Grignard reaction and $Li-NH_3$ reduction.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to National Institute of Science Communication and Information Resources.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 30 Jun 2008
Last Modified: 27 Aug 2008 13:28
URI: http://eprints.iisc.ernet.in/id/eprint/14366

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