ePrints@IIScePrints@IISc Home | About | Browse | Latest Additions | Advanced Search | Contact | Help

A Facile Conversion of Amides and Lactams to Thioamides and Thiolactams using Tetrathiomolybdate

Ilankumaran, Palanichamy and Ramesha, AR and Chandrasekaran, Srinivasan (1995) A Facile Conversion of Amides and Lactams to Thioamides and Thiolactams using Tetrathiomolybdate. In: Tetrahedron Letters, 36 (45). pp. 8311-8314.

[img] PDF
111.pdf
Restricted to Registered users only

Download (195Kb) | Request a copy

Abstract

Chloro iminium salts generated in situ from amides and lactams using $(COCl)_2$ or $POCl_3$ reacted very readily with the new sulfur transfer reagent, benzyltriethylammonium tetrathiomolybdate to afford the corresponding thioamides and thiolactams in exellent yields under mild reaction conditions.

Item Type: Journal Article
Additional Information: Copyright belongs to Elsevier B.V.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 24 Jun 2008
Last Modified: 19 Sep 2010 04:46
URI: http://eprints.iisc.ernet.in/id/eprint/14432

Actions (login required)

View Item View Item