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Electrode Kinetics of a Nickel-Cadmium cell and Failure-mode prediction- Constant voltage Charging

Prasad, Durga M and Sathyanarayana, S (1986) Electrode Kinetics of a Nickel-Cadmium cell and Failure-mode prediction- Constant voltage Charging. In: Indian Journal of Chemical Technology, 24 (7). pp. 361-371.

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Abstract

The response of a positive-limited Ni-Cd cell to constant voltage charging was theoretically analyzed taking into account the double-layer charging process; polarization effects due to mass transfer, charge transfer, and ohmic resistances in the cell; and self-discharge due to any internal electronic short. Expressions were obtained for charge transfer, mass transfer, and ohmic polarization. Experimental data obtained for several Ni-Cd cells indicate that the electrode reactions at the positive electrodes of the cells are controlled by mass transfer.

Item Type: Journal Article
Additional Information: Copyright of the article belongs to Council Scientific Industrial Reasearch.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 19 Jun 2008
Last Modified: 27 Aug 2008 13:29
URI: http://eprints.iisc.ernet.in/id/eprint/14461

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