Viswanatha, Ranjani and Santra, Pralay K and Dasgupta, Chandan and Sarma, DD (2007) Growth Mechanism of Nanocrystals in Solution: ZnO, a Case Study. In: Physics Review Letters, 98 (25). 255501-1-255501-4.
Restricted to Registered users only
Download (247Kb) | Request a copy
We investigate the mechanism of growth of nanocrystals from solution using the case of ZnO. Spanning a wide range of values of the parameters, such as the temperature and the reactant concentration that control the growth, our results establish a qualitative departure from the widely accepted diffusion controlled coarsening (Ostwald ripening) process quantified in terms of the Lifshitz-Slyozov-Wagner theory. Further, we show that these experimental observations can be qualitatively and quantitatively understood within a growth mechanism that is intermediate between the two well-defined limits of diffusion control and kinetic control.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to The American Physical Society.|
|Department/Centre:||Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Division of Physical & Mathematical Sciences > Physics
|Date Deposited:||03 Jul 2008|
|Last Modified:||19 Sep 2010 04:46|
Actions (login required)