ePrints@IIScePrints@IISc Home | About | Browse | Latest Additions | Advanced Search | Contact | Help

Kinetic currents in polarography. Part II. Spherical diffusion to the DME for pseudo-first order catalyzed processes and modification of Ilkovic equation

RS, Subrahmanya (1986) Kinetic currents in polarography. Part II. Spherical diffusion to the DME for pseudo-first order catalyzed processes and modification of Ilkovic equation. In: Journal of the Electrochemical Society of India, 35 (3). pp. 157-162.

Full text not available from this repository. (Request a copy)

Abstract

Introducing Ilkovic's limitation regarding the range of diffusion distance from the electrode surface into 3 dimensional spherical diffusion equation and combining it with the functional relationship, as also used by Kambara and Tachi, a differential equation for spherical diffusion to a growing electrode was formulated. Differential equations for spherical diffusion process to a growing Hg electrode for the cases involving chem. reactions occurring parallel to the electrode process were also formulated. The initial and the boundary conditions are given and the differential equation is solved by the Laplace transform method. A discussion of the modification of Ilkovic equation is also given

Item Type: Journal Article
Additional Information: Copyright to this article belongs to The Society,Bangalore. Journal of the Electrochemical Society of India currently does not have a website
Keywords: Kinetic currents;polarography;Spherical diffusion;DME;pseudo-first;catalyzed ;Ilkovic equation
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 04 Jul 2008
Last Modified: 27 Aug 2008 13:32
URI: http://eprints.iisc.ernet.in/id/eprint/14786

Actions (login required)

View Item View Item