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Synthesis and Spectroscopic Investigations of Complexes of Lanthanide Nitrates with Isoquinoline-2-oxide

Rajasekar, N (1986) Synthesis and Spectroscopic Investigations of Complexes of Lanthanide Nitrates with Isoquinoline-2-oxide. In: Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 16 (8). pp. 1109-1119.

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Abstract

Complexes of lanthanide nitrates with isoquinoline-2-oxide (IQNO) of the type $[Ln(IQNO)_3]$ $(NO_3)_3$, where Ln = Y and La-Yb have been synthesized and characterized by chemical analysis, conductance, infrared, proton NMR and electronic spectral data. Infrared and proton NMR data have been interpreted in terms of the coordination of the ligand to the tripositive lanthanide ion through the oxygen of the $N-O$ group. Conductance data along with the infrared studies indicate that all the nitrate groups are coordinated to the metal ion in a bidentate fashion. From the electronic spectral studies, a tentative coordination number of nine has been assigned to all the complexes under study.

Item Type: Journal Article
Additional Information: Copyright to this article belongs to Taylor & Francis.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 07 Jul 2008
Last Modified: 27 Aug 2008 13:32
URI: http://eprints.iisc.ernet.in/id/eprint/14806

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