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Charge-Transfer Satellites Next to Ligand Core Levels in the X-Ray Photoelectron Spectra of Metal Chlorides and Sulphides

Kamath, Vishnu P and Sarma, DD and Rao, CNR (1983) Charge-Transfer Satellites Next to Ligand Core Levels in the X-Ray Photoelectron Spectra of Metal Chlorides and Sulphides. In: Chemical Physics Letters, 101 (3). pp. 279-283.

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Abstract

Charge-transfer satellites due to $e_g \rightarrow e_g^*$ and $a_{1g} \rightarrow a_{1g}^*$ transitions have been observed for the first time next to the ligand core level peaks in the X-ray photoelectron spectra of metal chlorides and sulphides. These transitions are also seen next to the metal core levels in the case of the chlorides. Observation of these satellites, specially in the case of sulphides, underscores the crucial role of metal-ligand overlap in determining the intensity of charge-transfer satellites.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier.
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 16 Jul 2008
Last Modified: 19 Sep 2010 04:47
URI: http://eprints.iisc.ernet.in/id/eprint/15040

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