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A chemoselective aerobic oxidation of benzylic azides catalyzed by molybdenum xanthate in an aqueous medium

Maddani, Mahagundappa and Prabhu, Kandikere Ramaiah (2008) A chemoselective aerobic oxidation of benzylic azides catalyzed by molybdenum xanthate in an aqueous medium. In: Tetrahedron Letters, 49 (29-30). pp. 4526-4530.

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Abstract

A mild molybdenum-catalyzed, aerobic, chemoselective oxidation of benzylic azides to the corresponding aldehydes in an aqueous medium that tolerates a variety of functional groups including alcohols, esters,ketones, halides and olefins is described.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier.
Keywords: Benzyl azides;Molybdenum;Redox reactions;Aerobic oxidations;Chemoselectivity;Green chemistry.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 29 Jul 2008
Last Modified: 19 Sep 2010 04:48
URI: http://eprints.iisc.ernet.in/id/eprint/15332

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