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Exploratory Studies Towards AB-Ring System of Taxanes via Intramolecular Alkylation Reaction. Formation of Bicyclo[2.2.2]octanones in Preference to Bicyclo[5.3.1]undecanes

Srikrishna, A and Reddy, Jagadeeswara T and Kumar, Praveen P (2007) Exploratory Studies Towards AB-Ring System of Taxanes via Intramolecular Alkylation Reaction. Formation of Bicyclo[2.2.2]octanones in Preference to Bicyclo[5.3.1]undecanes. In: Indian journal of chemistry. Sect. B: Organic chemistry, including medical chemistry, 46 (9). pp. 1518-1525.

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Abstract

An intramolecular alkylation based approach has been explored for the enantiospecific construction of AB-ring system of taxanes starting from 3-allyl-4,4-dimethylcarvone, which however led only to bicyclo[2.2.2]octanones.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to CSIR
Keywords: terpenes;bridged compounds;ring closure reactions.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 30 Jul 2008
Last Modified: 06 Feb 2009 06:14
URI: http://eprints.iisc.ernet.in/id/eprint/15371

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