Srikrishna, Adusumilli and Pardeshi, Vijendra H and Satyanarayana, Gedu (2008) Enantiospecific approaches to bicyclic vibsanes: a ring-closing metathesis reaction-based strategy to functionalized bicyclo[4.3.1]decanes. In: Tetrahedron: Asymmetry, 19 (16). pp. 1984-1991.
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An enantiospecific synthesis of functionalized bicyclo[4.3.1]decane, the bicyclic core system present in some bi- and tricyclic vibsane diterpenoids, for example, vibsanin E, via an RCM reaction of 2,6-diallylcarvone derivatives is described. It has been further extended to the synthesis of tricyclo[6.4.1.01,5]tridecanes starting from 2,6,6-triallylcarvones.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to Elsevier.|
|Department/Centre:||Division of Chemical Sciences > Organic Chemistry|
|Date Deposited:||18 Dec 2008 12:32|
|Last Modified:||19 Sep 2010 04:51|
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