Srikrishna, Adusumilli and Pardeshi, Vijendra H and Satyanarayana, Gedu (2008) Enantiospecific approaches to bicyclic vibsanes: a ring-closing metathesis reaction-based strategy to functionalized bicyclo[4.3.1]decanes. In: Tetrahedron: Asymmetry, 19 (16). pp. 1984-1991.
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Abstract
An enantiospecific synthesis of functionalized bicyclo[4.3.1]decane, the bicyclic core system present in some bi- and tricyclic vibsane diterpenoids, for example, vibsanin E, via an RCM reaction of 2,6-diallylcarvone derivatives is described. It has been further extended to the synthesis of tricyclo[6.4.1.01,5]tridecanes starting from 2,6,6-triallylcarvones.
| Item Type: | Journal Article |
|---|---|
| Additional Information: | Copyright of this article belongs to Elsevier. |
| Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
| Date Deposited: | 18 Dec 2008 12:32 |
| Last Modified: | 19 Sep 2010 04:51 |
| URI: | http://eprints.iisc.ernet.in/id/eprint/16376 |
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