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In Situ Crystallography of KHSO4: Probing the Kinetic Pathway for the Evolution of a Pyrolysis Reaction in the Crystalline State

Swain, Diptikanta and Row, Tayur Guru N (2008) In Situ Crystallography of KHSO4: Probing the Kinetic Pathway for the Evolution of a Pyrolysis Reaction in the Crystalline State. In: Inorganic Chemistry, 47 (19). pp. 8613-8615.

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Official URL: http://pubs.acs.org/doi/abs/10.1021/ic801426f

Abstract

Variable-temperature in situ crystallography on $KHSO_{4}$ shows that the pyrolysis of $KHSO_{4}$ to $K_{2}S_{2}O_{7}$ occurs via a three-step kinetic pathway monitored by crystal-to-crystal phase transitions while providing an explanation for the high proton conductivity to be due to the disordered hydrogen-bonding pattern.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to American Chemical Society.
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 21 Aug 2009 05:11
Last Modified: 19 Sep 2010 04:52
URI: http://eprints.iisc.ernet.in/id/eprint/16451

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