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Construction of spiro[4.5]decane via ring-closing metathesis reaction: Formal synthesis of acorone and isoacorones

Srikrishna, A and Rao, Srinivasa M (2008) Construction of spiro[4.5]decane via ring-closing metathesis reaction: Formal synthesis of acorone and isoacorones. In: Indian journal of Chemistry Section-B, 47 (9). pp. 1423-1429.

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Official URL: http://nopr.niscair.res.in/handle/123456789/2004

Abstract

A Claisen rearrangement and RCM reaction based sequence has been developed for formal total synthesis of acorone and isoacorones starting from cyclohexane-1,4-dione. It has been further modified and avoided the protection-deprotection sequence in the second strategy.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Council of Scientific & Industrial Research.
Keywords: spiro[4.5]decane;acorones;RCM reaction;Claisen rearrangement; sesquiterpenes.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 17 Dec 2008 11:33
Last Modified: 17 Dec 2008 11:33
URI: http://eprints.iisc.ernet.in/id/eprint/16470

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