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Chiral synthons from α-pinene: enantioselective syntheses of bicyclo[3.3.0] and [3.2.1]octanones

Srikrishna, Adusumilli and Beeraiah, B and Satyanarayana, Gedo (2006) Chiral synthons from α-pinene: enantioselective syntheses of bicyclo[3.3.0] and [3.2.1]octanones. In: Tetrahedron-Asymmetry, 17 (10). pp. 1544-1548.

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Abstract

Enantioselective syntheses of bicyclo[3.3.0]octan-3-one, bicyclo[3.2.1]octan-3-one and bicyclo[3.2.1]octan-2-one derivatives were accomplished by employing a chiron based approach, using intramolecular rhodium carbenoid C-H insertion, acid catalysed cyclisation of alpha-diazo ketone and intramolecular type II carbonyl ene reactions as key steps.

Item Type: Journal Article
Additional Information: Coppyright of this article belongs to Elsavier
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 06 Mar 2009 11:26
Last Modified: 19 Sep 2010 04:54
URI: http://eprints.iisc.ernet.in/id/eprint/16956

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