Srikrishna, Adusumilli and Beeraiah, B and Satyanarayana, Gedo (2006) Chiral synthons from α-pinene: enantioselective syntheses of bicyclo[3.3.0] and [3.2.1]octanones. In: Tetrahedron-Asymmetry, 17 (10). pp. 1544-1548.
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Enantioselective syntheses of bicyclo[3.3.0]octan-3-one, bicyclo[3.2.1]octan-3-one and bicyclo[3.2.1]octan-2-one derivatives were accomplished by employing a chiron based approach, using intramolecular rhodium carbenoid C-H insertion, acid catalysed cyclisation of alpha-diazo ketone and intramolecular type II carbonyl ene reactions as key steps.
|Item Type:||Journal Article|
|Additional Information:||Coppyright of this article belongs to Elsavier|
|Department/Centre:||Division of Chemical Sciences > Organic Chemistry|
|Date Deposited:||06 Mar 2009 11:26|
|Last Modified:||19 Sep 2010 04:54|
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