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Formal total synthesis of (+/-)-herbertene-1,13-diol and (+/-)-alpha-herbertenol via Ireland ester Claisen rearrangement and RCM reaction sequence

Srikrishna, A and Lakshmi, BV (2005) Formal total synthesis of (+/-)-herbertene-1,13-diol and (+/-)-alpha-herbertenol via Ireland ester Claisen rearrangement and RCM reaction sequence. In: Synlett (7). pp. 1173-1175.

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Official URL: http://www.thieme-connect.de/DOI/DOI?10.1055/s-200...

Abstract

A combination of Ireland ester Claisen rearrangement and ring-closing metathesis (RCM) reactions has been employed for efficient formal total syntheses of herbertene-1,13-diol and α-herbertenol, sesquiterpenes containing two vicinal quaternary carbon atoms on a cyclopentane ring.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Thieme Medical Publishers.
Keywords: (±)-herbertene-1;13-diol;(±)-α-herbertenol;Ireland ester Claisen rearrangement.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 22 Jul 2009 07:56
Last Modified: 22 Jul 2009 07:56
URI: http://eprints.iisc.ernet.in/id/eprint/17082

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