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Stereoselective epoxide generation with cyclic rhodium carbenoids: A new access to spiro-indolooxiranes

Muthusamy, S and Gunanathan, C and Nethaji, M (2004) Stereoselective epoxide generation with cyclic rhodium carbenoids: A new access to spiro-indolooxiranes. In: Synlett (4). pp. 639-642.

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Official URL: http://www.thieme-connect.de/DOI/DOI?10.1055/s-200...

Abstract

The reaction of cyclic diazoamides with aryl aldehydes catalyzed by rhodium(II) acetate leads to intermolecular stereoselective epoxide ring formation. A series of spiro-indolooxiranes has been synthesized following the described method in a facile manner. The use of aryl dialdehydes in the course of reaction of cyclic diazoamide resulted the formation of bis-spiro-indolooxiranes.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Thieme Medical Publishers.
Keywords: carbenoids;diazo ketones;oxiranes;rhodium(II) acetate;spiro compounds.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 19 Dec 2008 18:08
Last Modified: 19 Dec 2008 18:08
URI: http://eprints.iisc.ernet.in/id/eprint/17314

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