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Supramolecular self assembly of a monomeric copper(II) complex of N-salicylidene-2-methoxyaniline forming three-dimensional closed and open channels

Reddy, Pattubala AN and Nethaji, Munirathinam and Chakravarty, Akhil R (2003) Supramolecular self assembly of a monomeric copper(II) complex of N-salicylidene-2-methoxyaniline forming three-dimensional closed and open channels. In: Inorganic Chemistry Communications, 6 (6). pp. 698-701.

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Abstract

A binary copper(II) complex [CuL2] (1), where HL is the Schiff base N-salicylidene-2-methoxyaniline, was prepared and structurally characterized. The complex which crystallizes in cubic space group Ia-3d with an unit cell dimension of 31.2451(17) , V = 30503(3) Angstrom(3), Z = 48, and refined to R-value of 0.0379 for 1700 data with I > 2sigma(I), shows a distorted four coordinate structure with a CuN2O2 chromophore. The complex self-assembles into a supramolecular architecture by non-covalent C-H...O interactions forming open and closed channels.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier Science B.V.
Keywords: copper(II) complex;Schiff base;X-ray structure;supramolecular architecture;lattice channels.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 26 Nov 2009 08:02
Last Modified: 19 Sep 2010 04:56
URI: http://eprints.iisc.ernet.in/id/eprint/17393

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